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Anthropogenic Drivers of Spatial Trends in Groundwater Quality in the Upper Athi River Basin of Kenya, East Africa

Received: 26 June 2024     Accepted: 10 July 2024     Published: 23 July 2024
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Abstract

Rapid urbanization and population growth in the upper Athi River basin in Kenya have increased the strain on the sub catchments water supply and sanitation situation. Due to increasing demand, inadequate supply of drinking water and lack of sanitation facilities, people in the sub-catchment are increasingly reliant on groundwater as a primary or supplementary water source. However, the use of on-site wastewater systems and agricultural pollution, mainly from runoff containing fertilizers, pesticides, herbicides, and faeces, pose a threat to groundwater in the sub catchment. Subsequently, the current study was conducted in the Thiririka sub catchment, Kiambu County, Kenya, to determine the safety of groundwater sources and to examine the factors influencing groundwater quality in the catchment area. This study assessed the influence of anthropogenic activities on the physical, chemical, and bacteriological quality of groundwater in the Upper Athi River basin of Kenya between April and June 2022. Twenty variables were analyzed and compared with water quality standards to determine hydro chemical characteristics, evidence of contamination, and suitability of groundwater. Shallow wells (SW) had higher concentrations of major ions and key parameters than boreholes (BH), such as alkalinity (7%), turbidity (96%), nitrates (92%), sulfates (48%), phosphates (93%), chlorides (77%), potassium (84%), sodium (30%) and fecal coliforms (99%) significant at p < 0.01. Concentrations of eleven water quality variables however were comparable in both systems. Farming, animal husbandry, and pit latrines were negatively but significantly correlated with the water quality of SW explaining substantial amounts of variation (≤ 45%) in concentrations of water quality variables. Ionic and coliform levels increased with decreasing distance and vice versa. IDW interpolation maps were generated in ArcGIS software to determine the spatial variability of groundwater quality in the basin. Anthropogenic activities such as pit latrines and animal husbandry impaired the quality of groundwater which in most cases was not potable.

Published in International Journal of Environmental Monitoring and Analysis (Volume 12, Issue 4)
DOI 10.11648/j.ijema.20241204.11
Page(s) 58-73
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Boreholes, Fecal Coliforms, IDW Interpolation, Groundwater Quality, Shallow Well, Upper Athi River Basin

References
[1] M. Saccò, S. Mammola, F. Altermatt, R. Alther, R. Bolpagni, A. Brancelj, D. Brankovits, C. Fišer, V. Gerovasileiou, C. Griebler, S. Guareschi, G. C. Hose, K. Korbel, E. Lictevout, F. Malard, A. Martínez, M. L. Niemiller, A. Robertson, K. C. Tanalgo, M. E. Bichuette, Š. Borko, T. Brad, M. A. Campbell, P. Cardoso, F. Celico, S. J. B. Cooper, D. Culver, T. Di Lorenzo, D. M. P. Galassi, M. T. Guzik, A. Hartland, W. F. Humphreys, R. L. Ferreira, E. Lunghi, D. Nizzoli, G. Perina, R. Raghavan, Z. Richards, A. S. P. S. Reboleira, M. M. Rohde, D. S. Fernández, S. I. Schmidt, M. van der Heyde, L. Weaver, N. E. White, M. Zagmajster, I. Hogg, A. Ruhi, M. M. Gagnon, M. E. Allentoft, R. Reinecke, Groundwater is a hidden global keystone ecosystem, Glob Chang Biol 30 (2024) e17066.
[2] I. J. Harrison, P. A. Green, T. A. Farrell, D. Juffe-Bignoli, L. Sáenz, C. J. Vörösmarty, Protected areas and freshwater provisioning: a global assessment of freshwater provision, threats and management strategies to support human water security, Aquat Conserv 26 (2016) 103–120.
[3] M. Velis, K. I. Conti, F. Biermann, Groundwater and human development: synergies and trade-offs within the context of the sustainable development goals, Sustain Sci 12 (2017) 1007–1017.
[4] P. Van Tuan, Y. Jiang, T. Stigter, Y. Zhou, Understanding groundwater use and vulnerability of rural communities in the Mekong Delta: The case of Tra Vinh province, Vietnam, Groundw Sustain Dev 25 (2024) 101095.
[5] N. Khatri, S. Tyagi, Influences of natural and anthropogenic factors on surface and groundwater quality in rural and urban areas, Front Life Sci 8 (2015) 23–39.
[6] S. M. Kithiia, S. M. Kithiia, Water Quality Degradation Trends in Kenya over the Last Decade, Water Quality Monitoring and Assessment (2012).
[7] S. M. Kithiia, G. S. Ongwenyi, Some problems of water quality degradation in the Nairobi River sub-basins in Kenya, Freshwater Contamination (Proceedings of Rabat Symposium S4, (1997). IAHS Publ. no. 243, 1997
[8] F. Genter Id, G. Lestari, P. Id, E. Suleeman, L. Darmajanti, C. Priadi, T. Foster, J. Willetts, Understanding household self-supply use and management using a mixed-methods approach in urban Indonesia, PLOS Water 2 (2023) e0000070.
[9] K. Fankhauser, D. Macharia, J. Coyle, S. Kathuni, A. McNally, K. Slinski, E. Thomas, Estimating groundwater use and demand in arid Kenya through assimilation of satellite data and in-situ sensors with machine learning toward drought early action, Science of The Total Environment 831 (2022) 154453.
[10] D. A. Ondigo, A. M. Kavoo, J. Kebwaro, D. A. Ondigo, A. M. Kavoo, J. Kebwaro, Water Resources and Management under Increasing Urban Demography: A Kenyan Perspective—A Review, J Water Resour Prot 10 (2018) 919–938.
[11] V. Balaram, L. Copia, U. S. Kumar, J. Miller, S. Chidambaram, Pollution of water resources and application of ICP-MS techniques for monitoring and management—A comprehensive review, Geosystems and Geoenvironment 2 (2023) 100210.
[12] [O. Al-Hashimi, K. Hashim, E. Loffill, T. Marolt Čebašek, I. Nakouti, A. A. H. Faisal, N. Al-Ansari, A Comprehensive Review for Groundwater Contamination and Remediation: Occurrence, Migration and Adsorption Modelling, Molecules 26 (2021).
[13] A. E. Onyango, M. W. Okoth, C. N. Kunyanga, B. O. Aliwa, Microbiological Quality and Contamination Level of Water Sources in Isiolo County in Kenya, J Environ Public Health 2018 (2018).
[14] R. K. Mishra, S. S. Mentha, Y. Misra, N. Dwivedi, Emerging pollutants of severe environmental concern in water and wastewater: A comprehensive review on current developments and future research, Water-Energy Nexus 6 (2023) 74–95.
[15] S. K. Abanyie, O. B. Apea, S. A. Abagale, E. E. Y. Amuah, E. D. Sunkari, Sources and factors influencing groundwater quality and associated health implications: A review, Emerg Contam 9 (2023) 100207.
[16] N. Akhtar, M. I. Syakir Ishak, S. A. Bhawani, K. Umar, Various Natural and Anthropogenic Factors Responsible for Water Quality Degradation: A Review, Water 2021, Vol. 13, Page 2660 13 (2021) 2660.
[17] D. J. Lapworth, D. C. W. Nkhuwa, J. Okotto-Okotto, S. Pedley, M. E. Stuart, M. N. Tijani, J. Wright, Urban groundwater quality in sub-Saharan Africa: current status and implications for water security and public health, Hydrogeol J 25 (2017) 1093–1116.
[18] Mogaka, H., Gichere, S., Davis, R. and Hirji, R. (2005) Climate Variability and Water Resources Degradation in Kenya: Improving Water Resources Development and Management. The World Bank, London.
[19] F. Mulwa, Z. Li, F. F. Fangninou, F. Mulwa, Z. Li, F. F. Fangninou, Water Scarcity in Kenya: Current Status, Challenges and Future Solutions, Open Access Library Journal 8 (2021) 1–15.
[20] S. M. Kithiia, S. M. Kithiia, A Critical Analysis of the Water Quality Impacts on Water Resources in the Athi River Drainage Basin, Kenya, Water Quality - Factors and Impacts (2021).
[21] S. O. Wandiga, Use and distribution of organochlorine pesticides. The future in Africa, Pure and Applied Chemistry 73 (2001) 1147–1155.
[22] O. R. Olonga, E. Ndunda, M. Makokha, Seasonal variations of physico-chemical and microbiological characteristics of groundwater quality in Ruiru, Kiambu county, Kenya, International Journal of Scientific and Research Publications 5 (2014).
[23] N. Alfarrah, K. Walraevens, Groundwater Overexploitation and Seawater Intrusion in Coastal Areas of Arid and Semi-Arid Regions, Water 2018, Vol. 10, Page 143 10 (2018) 143.
[24] J. O. Okullo, W. N. Moturi, G. M. Ogendi, Open Defaecation and Its Effects on the Bacteriological Quality of Drinking Water Sources in Isiolo County, Kenya, Environ Health Insights 11 (2017).
[25] S. M. Kithiia, Land use changes and their effects on sediment transport and soil erosion within the Athi drainage basin, Kenya, Human Impact on Erosion and Sedimentation (1997).
[26] APHA; AWWA and WEF, Standard Methods for the Examination of Water and Wastewater, American Public Works Association (2017) 1469.
[27] WHO, Guidelines for drinking-water quality, 4th edition, incorporating the 1st addendum. Geneva: World Health Organization. Geneva, Switzerland, World Health Organization (2017).
[28] H. H. Oyem, I. M. Oyem, A. I. Usese, Iron, manganese, cadmium, chromium, zinc and arsenic groundwater contents of Agbor and Owa communities of Nigeria, Springerplus 4 (2015) 1–10.
[29] C. T. Fader, Retrofitting Boreholes Contaminated With Iron In Rural Uganda, (2011).
[30] H. J. Smith, A. J. Zelaya, K. B. De León, R. Chakraborty, D. A. Elias, T. C. Hazen, A. P. Arkin, A. B. Cunningham, M. W. Fields, Impact of hydrologic boundaries on microbial planktonic and biofilm communities in shallow terrestrial subsurface environments, FEMS Microbiol Ecol 94 (2018) 191.
[31] K. Robey, G. Tredoux, L. Chevallier, Preventing Production Borehole Clogging by In-situ Iron Removal in South African Aquifer Systems Report to the WATER RESEARCH COMMISSION Obtainable from, (2014).
[32] E. K. Ahialey, Y. Serfoh-Armah, B. K. Kortatsi, Hydrochemical Analysis of Groundwater in the Lower Pra Basin of Ghana, J. Water Resource and Protection 2 (2010) 864–871.
[33] D. U. Ophori, J. Tóth, Patterns of Ground-Water Chemistry, Ross Creek Basin, Alberta, Canada, Groundwater 27 (1989) 20–26.
[34] M. O. Awoyemi, O. D. Ajama, S. A. Adekola, A. B. Arogundade, C. D. Fashina, G. O. Akinlade, J. A. O. Oyekunle, Water and sub-soil contamination in the coastal aquifers of Arogbo, Ondo State, Nigeria, J Hydrol Reg Stud 38 (2021) 100944.
[35] A. V. Kulinkina, J. D. Plummer, K. K. H. Chui, K. C. Kosinski, T. Adomako-Adjei, A. I. Egorov, E. N. Naumova, Physicochemical parameters affecting the perception of borehole water quality in Ghana, Int J Hyg Environ Health 220 (2017) 990.
[36] M. S. Islam, M. G. Mostafa, Occurrence, Source, and Mobilization of Iron, Manganese, and Arsenic Pollution in Shallow Aquifer, Geofluids 2023 (2023).
[37] M. Owor, A. Muwanga, C. Tindimugaya, R. G. Taylor, Hydrogeochemical processes in groundwater in Uganda: a national-scale analysis, Journal of African Earth Sciences 175 (2021) 104113.
[38] R. Bondu, V. Cloutier, E. Rosa, Occurrence of geogenic contaminants in private wells from a crystalline bedrock aquifer in western Quebec, Canada: Geochemical sources and health risks, J Hydrol (Amst) 559 (2018) 627–637.
[39] Y. Zhai, X. Cao, X. Xia, B. Wang, Y. Teng, X. Li, Elevated fe and mn concentrations in groundwater in the songnen plain, northeast china, and the factors and mechanisms involved, Agronomy 11 (2021) 2392.
[40] J. D. Hem, Study and interpretation of the chemical characteristics of natural water, Water Supply Paper (1985).
[41] F. A. Armah, Relationship Between Coliform Bacteria and Water Chemistry in Groundwater Within Gold Mining Environments in Ghana, Water Qual Expo Health 5 (2014) 183–195.
[42] C. Onyancha, Z. Getenga, Geochemistry of Groundwater in the Volcanic Rocks of Nairobi City, Type : Double Blind Peer Reviewed International Research Journal Publisher: Global Journals Inc 13 (2013).
[43] A. A. G. D. Amarasooriya, T. Kawakami, Removal of fluoride, hardness and alkalinity from groundwater by electrolysis, Groundw Sustain Dev 9 (2019) 100231.
[44] Y. Wang, R. Li, X. Wu, Y. Yan, C. Wei, M. Luo, Y. Xiao, Y. Zhang, Evaluation of Groundwater Quality for Drinking and Irrigation Purposes Using GIS-Based IWQI, EWQI and HHR Model, Water 2023, Vol. 15, Page 2233 15 (2023) 2233.
[45] V. Narasaiah, B. V. Rao, Groundwater quality of an hard rock aquifer in the Subledu Basin of Khammam district, India, Appl Water Sci 11 (2021) 1–21.
[46] M. C. Mangayayam, V. Alonso-de-Linaje, K. Dideriksen, D. J. Tobler, Effects of common groundwater ions on the transformation and reactivity of sulfidized nanoscale zerovalent iron, Chemosphere 249 (2020) 126137.
[47] K. G. Gebresilasie, G. G. Berhe, A. H. Tesfay, S. E. Gebre, Assessment of Some Physicochemical Parameters and Heavy Metals in Hand-Dug Well Water Samples of Kafta Humera Woreda, Tigray, Ethiopia, Int J Anal Chem 2021 (2021).
[48] B. O. Isiuku, C. E. Enyoh, Pollution and health risks assessment of nitrate and phosphate concentrations in water bodies in South Eastern, Nigeria, Environmental Advances 2 (2020) 100018.
[49] M. Zendehbad, M. Mostaghelchi, M. Mojganfar, P. Cepuder, W. Loiskandl, Nitrate in groundwater and agricultural products: intake and risk assessment in northeastern Iran, Environ Sci Pollut Res Int 29 (2022) 78603.
[50] Bijay-Singh, E. Craswell, Fertilizers and nitrate pollution of surface and ground water: an increasingly pervasive global problem, SN Applied Sciences 2021 3: 43(2021) 1–24.
[51] E. Abascal, L. Gómez-Coma, I. Ortiz, A. Ortiz, Global diagnosis of nitrate pollution in groundwater and review of removal technologies, Science of The Total Environment 810 (2022) 152233.
[52] P. K. Mbaka, J. K. Mwangi, C. K. Kiptum, Assessment of water quality in selected shallow wells of Keiyo Highlands, Kenya, African Journal of Science, Technology, Innovation and Development 9 (2017) 329–338.
[53] M. Abbas, L. Zhao, Y. Wang, Perspective Impact on Water Environment and Hydrological Regime Owing to Climate Change: A Review, Hydrology 2022, Vol. 9, Page 203 9 (2022) 203.
[54] P. U. Dao, A. G. Heuzard, T. X. H. Le, J. Zhao, R. Yin, C. Shang, C. Fan, The impacts of climate change on groundwater quality: A review, Science of The Total Environment 912 (2024) 169241.
[55] S. Bolan, L. P. Padhye, T. Jasemizad, M. Govarthanan, N. Karmegam, H. Wijesekara, D. Amarasiri, D. Hou, P. Zhou, B. K. Biswal, R. Balasubramanian, H. Wang, K. H. M. Siddique, J. Rinklebe, M. B. Kirkham, N. Bolan, Impacts of climate change on the fate of contaminants through extreme weather events, Science of The Total Environment 909 (2024) 168388.
[56] S. A. Aram, B. M. Saalidong, P. O. Lartey, Comparative assessment of the relationship between coliform bacteria and water geochemistry in surface and ground water systems, PLoS One 16 (2021).
[57] M. N. Welguś, T. Abiye, Surface water and groundwater interaction in the Vredefort Dome, South Africa, (2021).
[58] M. O. Dinka, W. Loiskandl, J. M. Ndambuki, Hydrochemical characterization of various surface water and groundwater resources available in Matahara areas, Fantalle Woreda of Oromiya region, J Hydrol Reg Stud 3 (2015) 444–456.
[59] G. Lutterodt, M. K. Miyittah, B. Addy, E. D. O. Ansa, M. Takase, Groundwater pollution assessment in a coastal aquifer in Cape Coast, Ghana, Heliyon 7 (2021) e06751.
[60] G. Lutterodt, J. van de Vossenberg, Y. Hoiting, A. K. Kamara, S. Oduro-Kwarteng, J. W. A. Foppen, Microbial Groundwater Quality Status of Hand-Dug Wells and Boreholes in the Dodowa Area of Ghana, Int J Environ Res Public Health 15 (2018).
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    Ashun, E., Tagoe, N. D. (2024). Anthropogenic Drivers of Spatial Trends in Groundwater Quality in the Upper Athi River Basin of Kenya, East Africa. International Journal of Environmental Monitoring and Analysis, 12(4), 58-73. https://doi.org/10.11648/j.ijema.20241204.11

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    Ashun, E.; Tagoe, N. D. Anthropogenic Drivers of Spatial Trends in Groundwater Quality in the Upper Athi River Basin of Kenya, East Africa. Int. J. Environ. Monit. Anal. 2024, 12(4), 58-73. doi: 10.11648/j.ijema.20241204.11

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    AMA Style

    Ashun E, Tagoe ND. Anthropogenic Drivers of Spatial Trends in Groundwater Quality in the Upper Athi River Basin of Kenya, East Africa. Int J Environ Monit Anal. 2024;12(4):58-73. doi: 10.11648/j.ijema.20241204.11

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  • @article{10.11648/j.ijema.20241204.11,
      author = {Ebenezer Ashun and Naa Dedei Tagoe},
      title = {Anthropogenic Drivers of Spatial Trends in Groundwater Quality in the Upper Athi River Basin of Kenya, East Africa
    },
      journal = {International Journal of Environmental Monitoring and Analysis},
      volume = {12},
      number = {4},
      pages = {58-73},
      doi = {10.11648/j.ijema.20241204.11},
      url = {https://doi.org/10.11648/j.ijema.20241204.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijema.20241204.11},
      abstract = {Rapid urbanization and population growth in the upper Athi River basin in Kenya have increased the strain on the sub catchments water supply and sanitation situation. Due to increasing demand, inadequate supply of drinking water and lack of sanitation facilities, people in the sub-catchment are increasingly reliant on groundwater as a primary or supplementary water source. However, the use of on-site wastewater systems and agricultural pollution, mainly from runoff containing fertilizers, pesticides, herbicides, and faeces, pose a threat to groundwater in the sub catchment. Subsequently, the current study was conducted in the Thiririka sub catchment, Kiambu County, Kenya, to determine the safety of groundwater sources and to examine the factors influencing groundwater quality in the catchment area. This study assessed the influence of anthropogenic activities on the physical, chemical, and bacteriological quality of groundwater in the Upper Athi River basin of Kenya between April and June 2022. Twenty variables were analyzed and compared with water quality standards to determine hydro chemical characteristics, evidence of contamination, and suitability of groundwater. Shallow wells (SW) had higher concentrations of major ions and key parameters than boreholes (BH), such as alkalinity (7%), turbidity (96%), nitrates (92%), sulfates (48%), phosphates (93%), chlorides (77%), potassium (84%), sodium (30%) and fecal coliforms (99%) significant at p < 0.01. Concentrations of eleven water quality variables however were comparable in both systems. Farming, animal husbandry, and pit latrines were negatively but significantly correlated with the water quality of SW explaining substantial amounts of variation (≤ 45%) in concentrations of water quality variables. Ionic and coliform levels increased with decreasing distance and vice versa. IDW interpolation maps were generated in ArcGIS software to determine the spatial variability of groundwater quality in the basin. Anthropogenic activities such as pit latrines and animal husbandry impaired the quality of groundwater which in most cases was not potable.
    },
     year = {2024}
    }
    

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  • TY  - JOUR
    T1  - Anthropogenic Drivers of Spatial Trends in Groundwater Quality in the Upper Athi River Basin of Kenya, East Africa
    
    AU  - Ebenezer Ashun
    AU  - Naa Dedei Tagoe
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    DO  - 10.11648/j.ijema.20241204.11
    T2  - International Journal of Environmental Monitoring and Analysis
    JF  - International Journal of Environmental Monitoring and Analysis
    JO  - International Journal of Environmental Monitoring and Analysis
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    PB  - Science Publishing Group
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    AB  - Rapid urbanization and population growth in the upper Athi River basin in Kenya have increased the strain on the sub catchments water supply and sanitation situation. Due to increasing demand, inadequate supply of drinking water and lack of sanitation facilities, people in the sub-catchment are increasingly reliant on groundwater as a primary or supplementary water source. However, the use of on-site wastewater systems and agricultural pollution, mainly from runoff containing fertilizers, pesticides, herbicides, and faeces, pose a threat to groundwater in the sub catchment. Subsequently, the current study was conducted in the Thiririka sub catchment, Kiambu County, Kenya, to determine the safety of groundwater sources and to examine the factors influencing groundwater quality in the catchment area. This study assessed the influence of anthropogenic activities on the physical, chemical, and bacteriological quality of groundwater in the Upper Athi River basin of Kenya between April and June 2022. Twenty variables were analyzed and compared with water quality standards to determine hydro chemical characteristics, evidence of contamination, and suitability of groundwater. Shallow wells (SW) had higher concentrations of major ions and key parameters than boreholes (BH), such as alkalinity (7%), turbidity (96%), nitrates (92%), sulfates (48%), phosphates (93%), chlorides (77%), potassium (84%), sodium (30%) and fecal coliforms (99%) significant at p < 0.01. Concentrations of eleven water quality variables however were comparable in both systems. Farming, animal husbandry, and pit latrines were negatively but significantly correlated with the water quality of SW explaining substantial amounts of variation (≤ 45%) in concentrations of water quality variables. Ionic and coliform levels increased with decreasing distance and vice versa. IDW interpolation maps were generated in ArcGIS software to determine the spatial variability of groundwater quality in the basin. Anthropogenic activities such as pit latrines and animal husbandry impaired the quality of groundwater which in most cases was not potable.
    
    VL  - 12
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    ER  - 

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